Probing heterocycle conformation with residual dipolar couplings.
نویسندگان
چکیده
Residual dipolar couplings (RDCs) obtained in a stretched polydimethylsiloxane gel are applied to determine the 7-membered ring conformation in a 2-phenyl-3-benzazepine derivative, and to simultaneously assign all methylene proton pairs using only (1)D(CH) RDCs and DFT molecular modelling data.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 32 شماره
صفحات -
تاریخ انتشار 2010